Katy Perry, Orlando Bloom, Chrissy Teigen and John Legend were just some of the stars who led the red carpet at the LuisaViaRoma for Unicef gala in Capri, Italy.
Looking very glamorous was Katy, 36, who donned a floor-length black gown with ruffle grey sleeves.
She wore her blonde locks into a neat bun, and added a pair of simple silver earrings to complete her look.
Meanwhile, her fiance Orlando, 44, looked very dapper in a white shirt and navy blazer, alongside a pair of cream-coloured trousers and beige shoes.
Chrissy, 35, looked fabulous in a shimmery sheer outfit, covered in sequins and featuring faux fur around the wrist.
Her husband John, 42, scrubbed up well in a white suit with black bow tie.
Other celebs in attendance included Heidi Klum, 48, who caught attention in a shiny silver dress, which featured a thigh-high split.
She posed on the carpet alongside her 17-year-old daughter Leni, who also brought the glitz and glam in a sequinned gold dress.
The supermodel was also pictured alongside her husband Tom Kaulitz, 31, who donned a glitzy blue suit and trainers.
Emily Ratajkowski, 30, looked daring in a black gown with puffed sleeves, which she paired with a matching set of heels.
She kept her accessories to a minimum to ensure full attention was on her outfit.
Emily also posed for pictures alongside Vanessa Hudgens, who also opted for a black number.
Dylan Penn, 30, the daughter of Sean Penn and Robin Wright, who also donned black, with her dress featuring a cut-out design near the left hip.
And Brooklyn Beckham’s ex-girlfriend Hana Cross, 23, exuded confidence in a silver wrap gown, which exposed her midriff.
She added a set of shiny gold heels and a pair of silver earrings to complete her look.
LuisaViaRoma annually hosts a gala in recognition of Unicef’s efforts, and this year is extra special as the event is honouring the third anniversary of the fashion brand’s partnership with the charity.
A number of stars host the gala, while a famous musical act makes a special appearance.
There was 66 guests in total, and each of their tables were treated to bottles of tequila from George Clooney’s brand Casamigos, while they could also order a range of cocktails from the bar.
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